Since cesium alum CsAl(SO 4) 2 recovered from the waste sulfuric acid vanadium catalyst may be directly utilized, or may be converted into the form of Cs 2 SO 4 through a smelting process including water leaching and then prepared into various compounds according to a purpose, the cesium alum CsAl(SO 4) 2 can be applied to various fields of ...

Vanadium and cesium were recovered from spent sulfuric acid catalysts, generated during a sulfuric acid manufacturing process, by an environmentally friendly …

Cesium alum One respect in which cesium (and rubidium) are outstanding among the alkali metals is the readiness with which it forms alums. Cesium alums are known for all of the Irivalenl cations that form alums. ... Rubidium is recovered from its ore lepidolite or pollucite. Mineral lepidolite is a lithium mica having a composition KRbLi(OH,F ...

Cesium is recovered from cesium alum, CsAl(SO4)2, by an aqueous conversion and precipitation reaction using a critical stoichiometric excess of a water-soluble permanganate to form solid cesium permanganate (CsMnO4) free from cesium alum. The other metal salts remain in solution, providing the final pH does not cause hydroxides of aluminum or ...

ABSTRACT Cesium is recovered from cesium alum, CsAl(SO4)2, by a two-reaction sequence in which the cesium alum is first dissolved in an aqueous hydroxide solution to form cesium alum hydroxide, CsAl(OH)3, and potassium sulfate, K2SO4. Part of the K2SO4 precipitates and is separated from the supernatant solution. In the second …

Since cesium alum CsAl(SO 4) 2 recovered from the waste sulfuric acid vanadium catalyst may be directly utilized, or may be converted into the form of Cs 2 SO 4 through a smelting process including water leaching and then prepared into various compounds according to a purpose, the cesium alum CsAl(SO 4) 2 can be applied to various fields of ...

Made available by U.S. Department of Energy Office of Scientific and Technical Information ...

Cesium present in the raffinate was precipitated as a cesium alum by adding aluminum sulfate, with a precipitation efficiency of more than 98% and with greater than 99% purity. The process developed in this study provides an efficient method for recovering vanadium and cesium from spent sulfuric acid catalysts using an eco-friendly and ...

cesium barium sulfate alum recovery Prior art date Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) Expired - Lifetime Application number US639366A Inventor Irwin E Johnson

The hot cesium alum solution including wash water was evaporated to a volume of about 5909.8 l (1300 gallons) and allowed to cool to room temperature. A decant of about 4546 l (1000 gallons) was taken. The cesium alum was …

Cesium alum is crystallized from the leach filtrate by stage cooling to 50 °C and then to 20 °C and roasted in the presence of 4% carbon. The residue is leached to produce cesium sulfate solution, ... Radiocesium can be recovered from fission products by …

A cesium sulfate product with a purity of 98.47 wt% was then recovered by evaporation and crystallization of the stripping solution Introduction Cesium is an important rare metal, playing an irreplaceable role in the fields of information industries, nuclear energy, aerospace technology, fluorescent materials and medicine (Le et al., 2013 ...

The purified alum crystals were then recovered by filtration and drying. Washing was not applied in order to avoid alum re-dissolution. Cesium Hydroxide and Cesium Formate Production. A 2 g sample of the synthesized aluminum cesium sulfate crystals was fully dissolved in 100 mL of water held at 90 °C throughout the duration of …

JPS6036335A JP59143427A JP14342784A JPS6036335A JP S6036335 A JPS6036335 A JP S6036335A JP 59143427 A JP59143427 A JP 59143427A JP 14342784 A JP14342784 A JP 14342784A JP S6036335 A JPS6036335 A JP S6036335A Authority JP Japan Prior art keywords cesium permanganate alum solution reaction Prior art date …

Cesium is recovered from cesium alum, CsAl(SO 4 ) 2, by an aqueous conversion and precipitation reaction using a critical stoichiometric excess of a water-soluble permanganate to form solid cesium permanganate (CsMnO 4 ) free from cesium alum. The other metal salts remain in solution, providing the final pH does not cause hydroxides of aluminum or …

The waste solution from cesium recovery is oxidized and neutralized to form stable iron–arsenate residues. The cesium alum is further treated to form high …

The cesium alum is recovered by filtration and re-dissolved in warm water. The solids remaining after the re-dissolution of the alum (substantially gypsum) is filtered out and discarded. ... The cesium alum precipitation from two SO 2 reductive leaching solutions was conducted without the addition of aluminum sulfate and the results are ...

The cesium alum is recovered by filtration and re-dissolved in warm water. The solids remaining after the re-dissolution of the alum (substantially gypsum) is filtered out and discarded. The cesium alum is then reformed by cooling. The pure cesium alum is dissolved again in hot water and treated with barium hydroxide in two stages.

Cesium present in the raffinate was precipitated as a cesium alum by adding aluminum sulfate, with a precipitation efficiency of more than 98% and with greater than 99% purity. The process developed in this study provides an efficient method for recovering vanadium and cesium from spent sulfuric acid catalysts using an eco …

The cesium alum may be recovered from the crystallizer slurry by a solid-liquid separation step. Cesium alum is water-soluble, so any washing of the alum is advantageously carried out so as to avoid re-solubilisation of the cesium alum. For example, in some embodiments, a minimal amount of washing may be carried out, and the wash water …

Cascadero Copper Corp. has developed a hydrometallurgical process to recover cesium from mineral samples of the Taron deposit in Argentina. Cesium was …

Cesium is recovered from cesium alum, CsAl(SO4)2, by an aqueous conversion and precipitation reaction using a critical stoichiometric excess of a water-soluble permanganate to form solid cesium permanganate (CsMnO4) free from cesium alum. The other metal salts remain in solution, providing the final pH does not cause hydroxides of aluminum or …

The cesium alum is then redissolved in water at an elevated temperature and reacted with an alkaline earth metal hydroxide, such as barium hydroxide or calcium hydroxide, to form an aluminum hydroxide precipitate together with precipitated barium sulfate or calcium sulfate. ... The cesium can be recovered from the supernatant …

The recovery of cesium has been studied using sulfuric acid leaching with recovery of cesium as alum. The waste solution from cesium recovery is oxidized and …

The cesium alum may be recovered from the crystallizer slurry by a solid-liquid separation step. Cesium alum is water-soluble, so any washing of the alum is advantageously carried out so as to avoid re-solubilisation of the cesium alum. For example, in some embodiments, a minimal amount of washing may be carried out, and …

94.7 % extraction of Cesium after 4 hours of leaching at 90 C with 250 g/L H2SO4 and 20 % Solids; Recovery of 97.8 to 99.4% of the Cesium as a Cesium Aluminum Sulfate …

Hydrometallurgical processes are provided for the recovery of metal values, including cesium, from epithermal mineral deposits, including pharmacosiderite-containing ores. Aspects of the process involve the preferential formation of a cesium alum, and preparation of cesium hydroxide from the cesium alum.

Process for recovering cesium from cesium alum. United States Patent RE32556. Abstract: Cesium is recovered from cesium alum, CsAl (SO 4) 2, by a two-reaction sequence in …

Hydrometallurgical processes are provided for the recovery of metal values, including cesium, from epithermal mineral deposits, including pharmacosiderite-containing ores. Aspects of the process involve the preferential formation of a cesium alum, and preparation of cesium hydroxide from the cesium alum.

The cesium can be recovered from the supernatant solution and converted into other cesium compounds. ... Cesium alum is reacted with calcium hydroxide, in an amount which is equimolar to the aluminum, and with a highly water soluble calcium salt, in an amount which is equimolar to the cesium. ...

EP0132656A2 EP84107903A EP84107903A EP0132656A2 EP 0132656 A2 EP0132656 A2 EP 0132656A2 EP 84107903 A EP84107903 A EP 84107903A EP 84107903 A EP84107903 A EP ...

The cesium alum is further treated to form high purity cesium hydroxide, which may be further processed to a range of cesium salts including cesium formate. The initial process developments for the Taron deposit are presented. ... The purified alum crystals were then recovered by filtration and drying. Washing was not applied in order to avoid ...

@ Cesium is recovered from cesium alum, CsAl(SO4)2, by a two-reaction sequence in which the cesium alum is first dissolved in an aqueous hydroxide solution to form cesium alum hydroxide, CsAl (OH)3, and potassium sulfate, K2SO4. part of the K2SO4precipitates and is separated from the supernatant solution. In the second reaction, a water-soluble ...

Cesium is recovered from cesium alum, CsAl(SO 4 ) 2, by an aqueous conversion and precipitation reaction using a critical stoichiometric excess of a water-soluble …