Using an ammonium sulfate to ore weight ratio of 3.5, first roasting temperature at 500 °C for 2 h, dosage of sodium sulfate of 4 g (per 10 g ore), followed by second roasting at 680 °C for 2 h, then water leaching at 95 °C for 2 h, nearly all of the Ni and Co, and 99.9% of the Cu and 1.1% of the Fe were extracted.