Full article: Pyrite – the firestone

A summary of pyrite's main properties is given in. Table 1. Herein, pyrite refers to the cubic sulphide FeS 2; pyrites is used as the umbrella term for a collection of yellowish metallic sulphides, see. Table 2. Note that marcasite is pyrite's unstable low temperature dimorph. Marcasite is a pyrites, it is not pyrite.

Chemical composition аnd morphology of pyrite and marcasite …

Pyrite and marcasite aggregates were found in a sample of blue silty clay from an exploration drill core at the northern edge of the Troyanovo North mine, Maritsa East lignite basin, Bulgaria. The aggregates have various sizes – from 50 µm (single crystal twins) to 0.5 cm (large twinned aggregates). Pyrite occurs as single cubic and …

Comparisons of pyrite variability from selected western …

@article{osti_7128369, title = {Petrographic characterization of Kentucky coals. Final report. Part V. Pyrite size/form/microlithotype distribution in western Kentucky prepared coals and in channel samples from western Kentucky and western Pennsylvania}, author = {Frankle, K A and Hower, J C}, abstractNote = {Pyrite and marcasite distribution has been …

Gold-bearing arsenian pyrite and marcasite and

Observed minimum Fe contents are 29.1 at.% in arsenian pyrite and marcasite from the Deep Star deposit and 31.3 at.% in synthetic arsenopyrite. The authors suggest that invisible Au in arsenian pyrite and marcasite from sediment-hosted Au deposits represents Au removed from ore fluids by chemisorption at As-rich, Fe-deficient surface sites and ...

Pyrite

Marcasite is a misnomer, referring to the mineral pyrite when it is faceted into small reflective stones and used in jewelry. Marcasite and pyrite …

Surface states and reactivity of pyrite and marcasite

Fig. 2 presents the S 2p spectra of pyrite and of two different marcasite surfaces measured with the same experimental parameters. The spectra were fitted using doublets with a fixed peak separation of 1.18 eV.The optimum ratio of the 2p 3/2 and 2p 1/2 intensity was determined to 0.47. The Gaussian and Lorentzian line widths were allowed …

Marcasite

Marcasite, often mistaken for pyrite, exudes a vintage glamour and refined elegance, making it a beloved choice in jewelry design. Its brassy golden textures and intricate features draw both the curious eye and the spiritual heart, while the humble marcasite cruises under the radar in popular crystal healing practices, hiding powerful ...

Pyrite, pseudomorph after marcasite with pyrite and …

Specimen size: 14 x 10 x 6 inches. dc.description.abstract. Several large clusters of intergrown (former) marcasite crystals that have been replaced by pyrite--on pyrite, on sphalerite. This mineral specimen is from the Eagle mine, Gilman mining district, Eagle County, Colorado.

The distinction of pyrite from marcasite in nodular growths

page 181 note 3 M. J. Buerger (Amer. Min., 1931, vol. 16, p. 361) in his work on the structure of marcasite used molybdenum radiation. The indices and intensities of spots on marcasite photographs obtained in the present work using Cu-Kr radiation are in substantial agreement with his data.

Pyrite & Marcasite 101 | Rock & Gem Magazine

Pyrite and marcasite are both iron sulfide minerals with the chemical formula FeS2. Pyrite crystallizes in the isometric system and commonly forms cubic …

The distinction of pyrite from marcasite in nodular …

More commonly the nodules exhibit small distorted octahedra which might easily be mistaken for marcasite. Indeed, in the past, many of these nodules from the …

On the Relationships between the Structure Types Pyrite, Marcasite…

DOI: 10.3891/ACTA.CHEM.SCAND.24-2983 Corpus ID: 93995040; On the Relationships between the Structure Types Pyrite, Marcasite, and Arsenopyrite. @article{Brostigen1970OnTR, title={On the Relationships between the Structure Types Pyrite, Marcasite, and Arsenopyrite.}, author={Gunnar Brostigen and Arne Kjekshus …

Experimental synthesis of auriferous arsenian pyrite/marcasite …

DOI: 10.1016/J.GEXPLO.2008.11.051 Corpus ID: 129072757; Experimental synthesis of auriferous arsenian pyrite/marcasite by pseudomorphic replacement of pyrrhotite @article{Xia2009ExperimentalSO, title={Experimental synthesis of auriferous arsenian pyrite/marcasite by pseudomorphic replacement of pyrrhotite}, author={Fang Xia and …

Kinetics of the marcasite-pyrite transformation: An infrared

Ansrn-lcr The kinetics of the solid-state transformation of marcasite to pyrite have been investigated using infrared spectroscopy. Kinetic analysis using the Johnson-Mehl or AvramiErofe'ev equation is based on measurements of infrared absorption intensity made on marcasite samples heated in the temperature range of 698-735 K. From the …

Synsedimentary, diagenetic, and metamorphic pyrite, …

Title: Synsedimentary, diagenetic, and metamorphic pyrite, pyrrhotite, and marcasite at the Homestake BIF-hosted gold deposit, South Dakota, USA; insights on Au-As ore genesis from textural and LA-ICP-MS trace element studies

Semiconductivity in pyrite, marcasite and arsenopyrite phases

DOI: 10.1016/0022-3697(65)90173-3 Corpus ID: 97832050; Semiconductivity in pyrite, marcasite and arsenopyrite phases @article{Hulliger1964SemiconductivityIP, title={Semiconductivity in pyrite, marcasite and arsenopyrite phases}, author={Fritz Hulliger and Etta Mooser}, journal={Journal of Physics and Chemistry of Solids}, …

Structural, optical and electrical impacts of marcasite in pyrite …

1. Introduction. Iron pyrite (cubic FeS 2) has attracted renewed attention as the most promising light-absorbing material for low-cost thin-film photovoltaic devices due to its abundance in the earth and lack of toxicity (Wadia et al., 2009a, Ennaoui et al., 1986, Ennaoui et al., 1993).In addition, the intrinsic properties of pyrite necessary for efficient …

Marcasite

Pyrite crystals are generally equant, and dominated by cubes, octahedrons and 12-sided pyritohedrons. Marcasite crystals are usually rectangular (tabular) with wedge-shaped ends and tend to form in star shaped, radiating or cockscomb groups. Marcasite is also much more restricted in occurrence than pyrite, forming only in low temperature, near ...

Energy bands in TX2 compounds with pyrite, marcasite, and arsenopyrite

The three structures: pyrite, marcasite, and arsenopyrite, are characterized by diatomic anions. These signal the formation of a single anion-pair bond, which means that the interacting orbitais per anion pair are split into a filled, bonding molecular o-^ orbital and an empty, antibonding molecular o^* orbital.

Marcasite

Pyrite and marcasite, on the other hand, have almost identical physical properties, making them tough to tell from each other. Let's go through their properties. Both are metallic and pale yellow to brassy yellow. Both can tarnish and be iridescent. Both are 6-6.5 on the Mohs' hardness scale. Neither have a particularly prominent cleavage ...

Replacement of pyrrhotite by pyrite and marcasite under …

title = "Replacement of pyrrhotite by pyrite and marcasite under hydrothermal conditions up to 220 degrees C: An experimental study of reaction textures and mechanisms", author = "Gujie Qian and Fang Xia and Joel Brugger and William Skinner and Jiafang Bei and Guorong Cren and Allan Pring",

Mineralization processes at the giant Jinding Zn–Pb deposit, …

The giant Jinding Zn–Pb deposit is in the Mesozoic–Cenozoic Lanping Basin of southern China and hosted by sandstone in the Early Cretaceous Jingxing Formation and limestone breccia and sandstone and gypsum in the Palaeocene Yunlong Formation. Mineral associations at the deposit are early (Stage 1) marcasite–sphalerite(–pyrite) …

Modular structures in sulphides: sphalerite/wurtzite-, pyrite/marcasite …

Abstract Invisible gold in natural and synthetic arsenian pyrite and marcasite correlates with anomalous As content and Fe deficiency, and high contents of invisible gold in most natural and all … Expand

Marcasite

Marcasite (FeS 2) is an iron sulfide that is sometimes called "white iron pyrite" because it has the same chemical formula as pyrite.It is distinct from pyrite because it crystallizes in an orthorhombic crystal system. This mineral is normally a pale brass-yellow color and crystals occur in association with Olentangy Shale and Ohio Shale in outcrops in …

First-principle calculations of interaction of O2 with pyrite

DOI: 10.1016/S1003-6326(16)64141-9 Corpus ID: 138111176; First-principle calculations of interaction of O2 with pyrite, marcasite and pyrrhotite surfaces @article{Zhao2016FirstprincipleCO, title={First-principle calculations of interaction of O2 with pyrite, marcasite and pyrrhotite surfaces}, author={Cuihua Zhao and Jian-hua …

Marcasite

marcasite and pyrite crystal groups occur in the dolostone bedrock up and down in the Mississippi River in Wisconsin and Minnesota. These minerals, however, have been …

Marcasite: The mineral marcasite information and …

Marcasite is the lesser known companion of the famous mineral Pyrite. Marcasite has the same chemical formula as Pyrite, but crystallize s in a different crystal system, thereby …

Marcasite vs Pyrite: Understanding the Key Differences

The answer is that both marcasite and pyrite are correct. However, marcasite specifically refers to the mineral iron sulfide, while pyrite is a broader term that can refer to a variety …

The mechanism and kinetics of the transformation …

Pyrite and marcasite, the two polymorphs of FeS 2, are among the most abundant metal sulfides in the Earth's upper crust, and play key roles in the global …

DFT study of interactions between calcium hydroxyl ions and pyrite …

DOI: 10.1016/J.APSUSC.2015.07.081 Corpus ID: 94304143; DFT study of interactions between calcium hydroxyl ions and pyrite, marcasite, pyrrhotite surfaces @article{Zhao2015DFTSO, title={DFT study of interactions between calcium hydroxyl ions and pyrite, marcasite, pyrrhotite surfaces}, author={Cuihua Zhao and Jian-hua Chen …

The pyrite—marcasite relation | American Mineralogist

Abstract. The control of the precipitation of pyrite and marcasite by chemical environment suggests that these two minerals are not a dimorphous pair in the usual sense of the …

[PDF] Identification of marcasite in pyrite FeS2 thin films …

In this study, we characterized FeS2 thin films grown by the non-vacuum spin-coating method. We annealed the samples under a sulfur atmosphere at different sulfurization temperatures. The phase transformation from marcasite-containing pyrite to pure pyrite occurs between 350 and 400 °C. The structural phase formation on the films …

Evaluating structure selection in the hydrothermal growth of …

In marcasite, we find that the spread of surface energies between the different facets is smaller than in pyrite, with the (010), (101), (110) and (111) facets all having low energies, in ...

Petrographic and chemical characteristics of pyrite-marcasite

Core recovered from Hess Rise contains concentrations of pyrite, marcasite, and barite in the lowermost meter of limestone (Unit II) and in the brecciated upper part of the underlying volcanic basement (Unit HI). Petrographic and chemical data indicate that the sulfide-barite assemblage in the limestone is mainly a product of low-temperature diagenetic processes.

Ore-forming processes of the Daqiao epizonal orogenic gold …

Sulfur isotopes determined from in situ LA-multicollector (MC)-ICP-MS analyses of hydrothermal pyrite and marcasite from the Daqiao deposit vary significantly from -31.3 to 22.0 ppm (delta (super 34) S values) but fall mostly between -10 to 10 ppm and provide important information on the source and evolution of sulfur and of the ore-forming fluids.

Marcasite and Pyrite

Pyrite is also exceptionally dense, with a specific gravity of 5.0 to 5.2. Only hematite has a higher density. Marcasite tends to be lighter in color, and is sometimes referred to as "white iron pyrite". Sometime marcasite has a greenish tint, or a multi-colored tarnish that is the result of oxidation. But marcasite has an unstable orthorhombic ...

Fluorite with Pyrite & Marcasite Crystal

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